Fluorescence up-conversion 70 fs (2)
back Location | Contact | |
Department of Physical Chemistry - Sciences II University of Geneva 30 quai Ernest-Ansermet 1211 Geneva 4 | Romain Letrun Tel. +41 22 379 36 58 Ro ma in .L et ru n@ un ig e. ch | |
Setup / Configuration | Literature | |
Time-resolved fluorescence apparatus based on a KML Ti:Sapphire oscillator producing ~30 fs pulses.
| Heisler, I. A., Kondo, M., Meech, S. R. (2009) Reactive Dynamics in Confined Liquids: Ultrafast Torsional Dynamics of Auramine O in Nanoconfined Water in Aerosol OT Reverse Micelles. J Phys Chem B. 113 (6), 1623-1631 »» | |
. | The top image shows the rotating sample cell (left/top) and the Schwarzschild objective (right/bottom) used to collect and focus the fluorescence. The bottom image shows pairs of chirped mirrors and wedges used to compress the laser pulses. The use of chirped mirrors allows to introduce negative group velocity dispersion (GVD), thus compensating the positive GVD induced by the dispersive elements included in the set-up. Pulses compression is necessary to improve the time resolution of the set-up. Time-resolved fluoresence spectra are reconstructed from the time profiles recorded at several wavelengths. |